Q2 (10 Marks) International Conventions
SSEP • Written Exam

(a) What are NOx & SOx limitations as per Annex VI of MARPOL.

(b) Briefly describe methods to control NOx emission and Sox emission.

Appeared In: Jan 2023

Verified Model Answer (Text Solution)

Structured for DG Shipping MEO Class II examination scoring criteria.

Exam Ready
Part (a)

NOx and SOx Limitations as per MARPOL Annex VI

NOx Limitations

The latest NOx emission Tier III has been enforced from January 1, 2016, in Emission Control Areas (ECAs). Tier II emission limits apply to engines installed on or after January 1, 2011, while diesel engines installed on or after January 1, 2000, are required to comply with Tier I emission limits.

The NOx emission limits (in g/kWh) are as follows:

Tier

Ship Construction Date On or After

Total Weighted Cycle Emission Limit (Engine's Rated Speed, n<130 rpm)

I

Jan 1, 2000

17.0

II

Jan 1, 2011

44×n^−0.23 (Maximum 14.4)

III

Jan 1, 2016

3.4

Note: NOx Tier III is applicable only in ECAs. Outside ECAs, Tier II limits apply.

SOx Limitations

The fuel oil sulphur limit for SOx control is as follows:

Outside ECA

Inside ECA

Content

Date

Content

Date

4.5% m/m

prior to Jan 1, 2012

1.5% m/m

prior to July 1, 2010

3.5% m/m

on or after Jan 1, 2012

1.00% m/m

on or after July 1, 2010

0.5% m/m

on or after Jan 1, 2020

0.1% m/m

on or after Jan 1, 2015

Part (b)

Methods to Control NOx and SOx Emissions

Methods to Control NOx Emissions

NOx control methods can be divided into two categories:

1. Primary Methods:

Primary NOx reduction measures are implemented within the combustion chamber itself to reduce nitrogen oxide (NOx) emissions at their source. These measures include the use of:

  • Low-NOx burners
  • Improved fuel oil quality
  • Combustion air preheating
  • Fuel-water emulsions

These techniques aim to lower the peak combustion temperature, thereby reducing NOx formation. While highly effective, primary methods typically require significant investment and can affect engine performance and operational characteristics.

2. Secondary Methods:

  • Selective Catalytic Reduction (SCR): In this system, urea or ammonia is injected into the exhaust gas before it passes through a unit consisting of a special catalyst layer. A chemical reaction between urea/ammonia and NOx reduces NOx to nitrogen (N2​) at temperatures between 300-400°C. SCR units are typically installed between the manifold and the turbocharger.
  • Exhaust Gas Recirculation (EGR): In this system, a portion of the exhaust gas is recirculated to the scavenge air receiver after passing it through a scrubber unit. EGR is claimed to achieve around 50-60% NOx reduction from Tier I levels. However, the discharge of the cleaning water from the scrubber requires treatment.
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